Ch 205 Lab Help

Ideal Gas Law

Your report should contain the usual brief intro (what was being studied and how it was studied), as well as the usual brief methods section (don't forget to make a proper reference to the lab manual!)

Part 1: Boyle's Law

Export your Logger Pro pressure-volume data into Excel. You'll probably want to convert pressures from kPa into atm and volumes into liters before plotting. Here's a sample of what Fig 1 should resemble:

Fig 2 should be a plot of pressure vs 1/volume, as shown here. Fit a trendline to the data and print the equation of the trendline on the plot:

Next, calculate moles of air in the syringe. Use your first pressure-volume data pair (pressure in atm, volume in liters.) Assume ideal gas behavior. If you didn't measure room temperature, use 21.5oC for T (we measured it.) You should get something on the order of 7x10-4 moles of air.

An interesting exercise to do now: Boyle's Law states that PV=Constant for a fixed quantity of gas at constant T. Use excel and each of your P-V points to see if P*V is constant to at least a few decimal places for all of your data. Comment on this in your discussion.

Another interesting exercise: the ideal gas law states that P = nRT/V. The plot above (Fig 2) of P vs 1/V is linear; therefore, for an ideal gas, the slope of this plot should equal nRT. You calculated moles of air (n) above, and you know the temperature. Set nRT = slope of the trendline, and solve for R (the data set here gave 0.07606 L atm/mol K. Calculate R from your data and compare your value to 0.08206 Liter atm/mol K.)

Part 2 Pressure-Temperature relationship

Plot your data as pressure (atm) vs temperature (oC) and pressure vs Kelvin temperature (K = oC + 273.15). These plots are shown as Figs 3 and 4.

The relationship between P and T is nominally linear, so we write P=CT, where C is a constant. Calculate the value of the constant C for each of your P-T data pairs (Take P/T=C) and comment on how constant this quantity remains through the experiment.

Use the P vs Kelvin plot to calculate a value for absolute zero. Use the equation of the trendline to find the temperature (X-value) where the pressure (y-value) equals zero (i.e., in the trendline on Fig 4 above, set y=0 and solve for x.) What value do you obtain?

Also use the equation of the trendline to predict the pressure at 200 K and 400 K (plug the temperatures in for x and calculate the pressures.) What happens to the pressure when the temperature is doubled?

In your discussion, please mention why pressure increases with temperature - propose an explanation in terms of the kinetic energies of the particles which make up the gas.


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